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For which reaction will Kp = Kc?


A) S(s) + O2(g) ⇌ SO2(g)
B) 2 HgO(s) ⇌ Hg(l) + O2(g)
C) CaCO3(s) ⇌ CaO(s) + CO2(g)
D) H2CO3(s) ⇌ H2O(l) + CO2(g)
E) 2 H2O(l) ⇌ 2 H2(g) + O2(g)

F) B) and D)
G) None of the above

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The equilibrium constant for the reaction A(g) LB(g) is 102.A reaction mixture initially contains [A] = 10.1 M and [B] = 0.0 M.Which statement is true at equilibrium?


A) The reaction mixture contains [A] = 10.0 M and [B] = 0.10 M.
B) The reaction mixture contains [A] = 0.10 M and [B] = 10.0 M.
C) The reaction mixture contains [A] = 0.55 M and [B] = 0.55 M.
D) The reaction mixture contains [A] = 1.0 M and [B] = 100.0 M.

E) B) and D)
F) None of the above

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Why aren't solids or liquids included in an equilibrium expression?

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The equilibrium constant relates different concentrations of reactants and products to one another.Since the concentrations of liquids and solids are constant,their concentration(s)becomes part of the constant value of the equilibrium constant.

The equilibrium constant is given for one of the reactions below.Determine the value of the missing equilibrium constant. H2(g) + Br2(g) ⇌ 2 HBr(g) Kc = 3.8 × 104 2 HBr(g) ⇌ H2(g) + Br2(g) Kc = ?


A) 1.9 × 104
B) 5.3 × 10-5
C) 2.6 × 10-5
D) 6.4 × 10-4
E) 1.6 × 103

F) B) and D)
G) B) and E)

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At equilibrium in a 10.0 L vessel,there are 7.6 × 10-2 moles of SO2,8.6 × 10-2 moles of O2,and 8.2 × 10-2 moles of SO3.What is the equilibrium constant (Kc) for the reaction: 2SO2(g) + O2(g) ⇌ 2SO3(g)


A) 7.4 × 10-3
B) 12.5
C) 135
D) 13.5

E) A) and C)
F) None of the above

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The equilibrium constant is given for one of the reactions below.Determine the value of the missing equilibrium constant. 2 SO2(g) + O2(g) ⇌ 2 SO3(g) Kc = 1.7 × 106 SO3(g) ⇌ 1/2 O2(g) + SO2(g) Kc = ?


A) 3.4 × 102
B) 8.5
C) 1.3 × 103
D) 1.2 × 10-6
E) 7.7 × 10-4

F) A) and D)
G) D) and E)

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Kc is 1.67 × 1020 at 25°C for the formation of iron(III) oxalate complex ion: Fe3+(aq) + 3 C2O42-(aq) ⇌ [Fe(C2O4) 3]3-(aq) . If 0.0200 M Fe3+ is initially mixed with 1.00 M oxalate ion,what is the concentration of Fe3+ ion at equilibrium?


A) 1.44 × 10-22 M
B) 0.0100 M
C) 8.35 × 1019 M
D) 6.94 × 1021 M

E) All of the above
F) A) and B)

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Consider the following reaction at equilibrium.What effect will adding water have on the system? CO2(g) + 2 H2O(l) ⇌ CH4(g) + 2 O2(g) ΔH° = +890 kJ


A) The reaction will shift to the left in the direction of reactants.
B) The equilibrium constant will decrease.
C) The equilibrium constant will increase.
D) The reaction will shift to the right in the direction of products.
E) No effect will be observed.

F) C) and D)
G) A) and E)

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For the reaction: N2(g) + 2 O2(g) ⇌ 2 NO2(g) ,Kc = 8.3 × 10-10 at 25°C.What is the concentration of N2 gas at equilibrium when the concentration of NO2 is five times the concentration of O2 gas?


A) 3.3 × 10-11 M
B) 1.7 × 10-10 M
C) 6.0 × 109 M
D) 3.0 × 1010 M

E) A) and D)
F) A) and C)

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Match the following. -K << 1


A) Reaction will favor formation of reactants.
B) Reaction does not strongly favor reactants or products.
C) Reaction favors formation of more products.
D) Reaction has a larger amount of products than reactants.
E) Reaction is at equilibrium.

F) A) and E)
G) B) and C)

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Determine the value of Kc for the following reaction if the equilibrium concentrations are as follows: [PCl5]eq = 0.56 M,[PCl3]eq = 0.23 M,[Cl2]eq = 4.4 M. PCl5(g) ⇌ PCl3(g) + Cl2(g)


A) 1.8
B) 0.93
C) 0.55
D) 1.1
E) 0.76

F) C) and D)
G) A) and D)

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Express the equilibrium constant for the following reaction. H2(g) + Br2(g) ⇌ 2 HBr(g)


A) K = Express the equilibrium constant for the following reaction. H<sub>2</sub>(g) + Br<sub>2</sub>(g) ⇌ 2 HBr(g)  A) K =   B) K =   C) K =   D) K =   E) K =
B) K = Express the equilibrium constant for the following reaction. H<sub>2</sub>(g) + Br<sub>2</sub>(g) ⇌ 2 HBr(g)  A) K =   B) K =   C) K =   D) K =   E) K =
C) K = Express the equilibrium constant for the following reaction. H<sub>2</sub>(g) + Br<sub>2</sub>(g) ⇌ 2 HBr(g)  A) K =   B) K =   C) K =   D) K =   E) K =
D) K = Express the equilibrium constant for the following reaction. H<sub>2</sub>(g) + Br<sub>2</sub>(g) ⇌ 2 HBr(g)  A) K =   B) K =   C) K =   D) K =   E) K =
E) K = Express the equilibrium constant for the following reaction. H<sub>2</sub>(g) + Br<sub>2</sub>(g) ⇌ 2 HBr(g)  A) K =   B) K =   C) K =   D) K =   E) K =

F) C) and D)
G) B) and E)

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Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium concentration of SO3(g) . 2 SO2(g) + O2(g) ⇌ 2 SO3(g) Kc = 1.7 × 108 [SO2]eq = 0.0034 M [O2]eq = 0.0018 M


A) 1.9 M
B) 1.0 × 103 M
C) 0.53 M
D) 9.6 × 10-4 M
E) 0.73 M

F) B) and E)
G) A) and D)

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A

What will happen to the following exothermic reaction at equilibrium if the pressure is raised? N2(g) + 3H2(g) ⇌ 2NH3(g)


A) Less NH3 will be produced.
B) More N2 and H2 will be produced.
C) There will be no change in concentrations.
D) More NH3 will be produced.

E) All of the above
F) A) and D)

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Consider the following reaction at equilibrium.What effect will adding 1 atm of Ar to the reaction mixture have on the system? 2 H2S(g) + 3 O2(g) ⇌ 2 H2O(g) + 2 SO2(g)


A) The reaction will shift to the right in the direction of products.
B) No effect will be observed.
C) The reaction will shift to the left in the direction of reactants.
D) The equilibrium constant will decrease.
E) The equilibrium constant will increase.

F) A) and D)
G) B) and C)

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Match the following. -Q < K


A) Reaction will favor formation of reactants.
B) Reaction does not strongly favor reactants or products.
C) Reaction favors formation of more products.
D) Reaction has a larger amount of products than reactants.
E) Reaction is at equilibrium.

F) A) and B)
G) A) and C)

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Match the following. -Q >> 1


A) Reaction will favor formation of reactants.
B) Reaction does not strongly favor reactants or products.
C) Reaction favors formation of more products.
D) Reaction has a larger amount of products than reactants.
E) Reaction is at equilibrium.

F) A) and B)
G) C) and D)

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Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium concentration of H2O(g) . C2H4(g) + H2O(g) ⇌ C2H5OH(g) Kc = 9.0 × 103 [C2H4]eq = 0.015 M [C2H5OH]eq = 1.69 M


A) 9.9 × 10-7 M
B) 80.M
C) 1.0 M
D) 1.68 M
E) 0.013 M

F) C) and D)
G) A) and B)

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The reaction below has a Kc value of 1.0 × 1012.What is the value of Kp for this reaction at 500 K? 2 SO2(g) + O2(g) ⇌ 2 SO3(g)


A) 4.2 × 10-11
B) 1.0 × 1012
C) 2.4 × 10-12
D) 4.1 × 1013
E) 2.4 × 1010

F) A) and E)
G) A) and D)

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Phosphorous trichloride and phosphorous pentachloride equilibrate in the presence of molecular chlorine according to the reaction: PCl3(g) + Cl2(g) ⇌ PCl5(g) An equilibrium mixture at 450 K contains PPCl3 = 0.124 atm, PCl2 = 0.157 atm,and PPCl5 = 1.30 atm.What is the value of Kp at this temperature?


A) 66.7
B) 1.50 × 10-2
C) 2.53 × 10-2
D) 1.02
E) 4.63

F) B) and E)
G) A) and C)

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A

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