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What is the pH of the final solution when 25 mL of 0.023 M HCl has been added to 35 mL of 0.040 M HCl at 25°C?


A) 3.22
B) 1.81
C) 1.48
D) 2.70
E) 3.41

F) A) and B)
G) A) and C)

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Which are the Brønsted-Lowry bases in the following equilibrium? HCOO-(aq) + H2O(l) Which are the Brønsted-Lowry bases in the following equilibrium? HCOO<sup>-</sup>(aq) + H<sub>2</sub>O(l)    HCOOH(aq) + OH<sup>-</sup>(aq)  A) HCOO<sup>-</sup> and OH<sup>-</sup> B) H<sub>2</sub>O and OH<sup>-</sup> C) H<sub>2</sub>O,HCOOH,and OH<sup>-</sup> D) HCOO<sup>-</sup> and HCOOH E) H<sub>2</sub>O and HCOOH HCOOH(aq) + OH-(aq)


A) HCOO- and OH-
B) H2O and OH-
C) H2O,HCOOH,and OH-
D) HCOO- and HCOOH
E) H2O and HCOOH

F) All of the above
G) A) and D)

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Which solution has the highest pH?


A) 0.10 M HBr(aq)
B) 0.10 M HI(aq)
C) 0.10 M HF(aq)
D) 0.10 M HCl(aq)
E) 0.10 M HClO4(aq)

F) C) and D)
G) B) and C)

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The equilibrium constant for the autonionization of water (shown below) increases with increasing temperature,from 1.01 x10-14 at 25°C to 5.31 x10-14 at 50°C. H2O(l) + H2O(l) The equilibrium constant for the autonionization of water (shown below) increases with increasing temperature,from 1.01 x10<sup>-14</sup> at 25°C to 5.31 x10<sup>-14</sup> at 50°C. H<sub>2</sub>O(l) + H<sub>2</sub>O(l)    H<sub>3</sub>O<sup>+</sup>(aq) + OH<sup>-</sup>(aq)  Which of the following statements is consistent with this behaviour? A) The autoionization of water is an endothermic reaction. B) The autoionization of water is an exothermic reaction. C) The hydronium ion concentration at equilibrium increases with increasing temperature. D) The hydronium ion concentration at equilibrium decreases with increasing temperature. E) Both A and C. H3O+(aq) + OH-(aq) Which of the following statements is consistent with this behaviour?


A) The autoionization of water is an endothermic reaction.
B) The autoionization of water is an exothermic reaction.
C) The hydronium ion concentration at equilibrium increases with increasing temperature.
D) The hydronium ion concentration at equilibrium decreases with increasing temperature.
E) Both A and C.

F) A) and D)
G) B) and D)

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Rank the following in order of decreasing acid strength: H2O,H2S,H2Se,H2Te


A) H2Te > H2Se > H2S > H2O
B) H2O > H2S > H2Se > H2Te
C) H2Se > H2Te > H2S > H2O
D) H2S > H2Te > H2Se > H2O
E) H2Se > H2S > H2Te > H2O

F) A) and B)
G) B) and C)

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Which of the following statements is incorrect?


A) One reason why HCl is a stronger acid than HF is that the H-Cl bond is weaker than the H-F bond.
B) F- is a stronger base than Cl-.
C) One reason why HCl is a stronger acid than HF is that Cl is more electronegative than F.
D) The acids HBr and HI both appear equally strong in water.
E) One reason why HCl is a stronger acid than HF is that Cl has a larger atomic radius than F.

F) B) and C)
G) D) and E)

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The pOH of a solution is 5.72 .What is its hydronium-ion concentration?


A) 5.2 × 105 M
B) 5.2 × 10-9 M
C) 1.9 × 10-6 M
D) 5.72 M
E) 3.3 × 10-3 M

F) A) and B)
G) A) and C)

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What is the pH of a 0.0052 M CaOH solution?


A) 8.74
B) 11.72
C) 2.28
D) 5.26
E) 16.28

F) A) and B)
G) A) and E)

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Which of the following is not an example of an acid-base reaction?


A) Al(OH) 3(s) + 3H+(aq) →→ Al3+(aq) + 3H2O(l)
B) C2H6(g) → →→→→→C2H4(g) + H2(g)
C) MgO(s) + CO2(g) →→ MgCO3(s)
D) Al(OH) 3(s) + OH-(aq) →→→→→ Al(OH) 4-(aq)
E) CN-(aq) + H2O(l) Which of the following is not an example of an acid-base reaction? A) Al(OH) <sub>3</sub>(s) + 3H<sup>+</sup>(aq) →→ Al<sup>3+</sup>(aq) + 3H<sub>2</sub>O(l)  B) C<sub>2</sub>H<sub>6</sub>(g) → →→→→→C<sub>2</sub>H<sub>4</sub>(g) + H<sub>2</sub>(g)  C) MgO(s) + CO<sub>2</sub>(g) →→ MgCO<sub>3</sub>(s)  D) Al(OH) <sub>3</sub>(s) + OH<sup>-</sup>(aq) →→→→→ Al(OH) <sub>4</sub><sup>-</sup>(aq)  E) CN<sup>-</sup>(aq) + H<sub>2</sub>O(l)    HCN(aq) + OH<sup>-</sup>(aq) HCN(aq) + OH-(aq)

F) D) and E)
G) A) and B)

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Which of the following is the strongest acid in aqueous solution?


A) H3AsO4
B) H3PO4
C) H3PO3
D) H3SbO4
E) H3AsO3

F) B) and E)
G) B) and D)

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What is the pH of a 0.0072 M hydrochloric acid solution?


A) 4.93
B) 11.86
C) 7.00
D) 9.07
E) 2.14

F) A) and C)
G) B) and C)

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Which of the following reactions is not product-favored?


A) NaOH(aq) → Na+(aq) + OH-(aq)
B) NH3(aq) + H2O(l) → NH4+(aq) + OH-(aq)
C) HClO4(aq) + H2O(l) → H3O+(aq) + ClO4-(aq)
D) HCl(aq) + H2O(l) → H3O+(aq) + Cl-(aq)
E) H2SO4(aq) + H2O(l) → H3O+(aq) + HSO4-(aq)

F) A) and E)
G) All of the above

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What is the concentration of H3O+ and OH ion in pure water at 25 °C?​


A) ​1.8 × 10−7 M,3.2 × 10−7 M
B) ​2.0 × 10−7 M,4.0 × 10−7 M
C) ​3.0 × 10−7 M,2.0 × 10−7 M
D) ​2.0 × 10−7 M,1.5 × 10−7 M
E) ​1.0 × 10−7 M,1.0 × 10−7 M

F) C) and D)
G) B) and C)

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A solution has a pH value of 3.66.What is the pOH for this solution?


A) 7.00
B) 3.83
C) 3.66
D) 2.19
E) 10.34

F) None of the above
G) D) and E)

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Rank the following in order of decreasing acid strength in aqueous solution: HBr,HOCl,HOBr,HOI.


A) HBr > HClO > HBrO > HIO
B) HIO > HBrO > HClO > HBr
C) HBr > HIO > HBrO > HClO
D) HClO > HBr > HBrO > HIO
E) HClO > HBrO > HBr > HIO

F) C) and D)
G) A) and E)

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What is the pOH of a solution prepared by dissolving 0.591 g of KOH(s) in 7.50 L of water?


A) 11.148
B) 2.852
C) 1.977
D) 12.023
E) 7.000

F) C) and E)
G) None of the above

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Which of the following pairs of species is not a conjugate acid-base pair?


A) HOCl,OCl-
B) HNO2,NO2+
C) O2-,OH-
D) HSO4-,SO42-
E) H2CO3,HCO3-

F) C) and D)
G) B) and D)

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What is the equilibrium concentration of amide ion (NH2-) in liquid ammonia at 25°C? ("am" = dissolved in ammonia) 2NH3(l) What is the equilibrium concentration of amide ion (NH<sub>2</sub><sup>-</sup>) in liquid ammonia at 25°C? ( am  = dissolved in ammonia)  2NH<sub>3</sub>(l)    NH<sub>4</sub><sup>+</sup>(am) + NH<sub>2</sub><sup>-</sup>(am) ; K<sub>c</sub> = 1.8 × 10<sup>-24</sup> at 25°C A) 2.6 × 10<sup>-12</sup> M B) 3.6 × 10<sup>-24</sup> M C) 1.3 × 10<sup>-12</sup> M D) 1.8 × 10<sup>-24</sup> M E) 9.0 × 10<sup>-25</sup> M NH4+(am) + NH2-(am) ; Kc = 1.8 × 10-24 at 25°C


A) 2.6 × 10-12 M
B) 3.6 × 10-24 M
C) 1.3 × 10-12 M
D) 1.8 × 10-24 M
E) 9.0 × 10-25 M

F) All of the above
G) C) and D)

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A solution in which the pH is 1.5 would be described as


A) neutral.
B) very acidic.
C) slightly basic.
D) slightly acidic.
E) very basic.

F) C) and D)
G) A) and B)

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Which of the following species is amphiprotic in aqueous solution?


A) CH3NH2
B) H3O+
C) NH4+
D) F−
E) HSO4-

F) A) and B)
G) B) and E)

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