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Exam 5: Stereoisomerism

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Question 21

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Assign the following stereocenter as having the R or S absolute configuration.

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Question 22

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What is the relationship between the following two molecules?

A) enantiomers
B) diastereomers
C) identical
D) constitutional Isomers

E) C) and D)
F) B) and C)

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Question 23

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Is the following alkene cis, trans, or neither?

Convert the following Fischer projection into a wedge/dash drawing.

Draw the meso isomer of the following compound.

What is the relationship between the two structures shown?

Which of the following strategies will NOT be an effective way to separate enantiomers?

What is the relationship between the following two compounds?

Is the alkene on the left in the molecule below E, Z, or neither?

Locate the chirality center(s) in the following compound.

Draw the structure of the compound (S)-3-methylheptane.

What is the relationship between the following two compounds?

What is the percentage of the S enantiomer in a sample of carvone that has a specific rotation of 30, given that the specific rotation of (R) -carvone is −61?

Locate the chirality center(s) in the following compound.

Rank the following from highest to lowest priority according to the Cahn-Ingold-Prelog system. I. -CH₂CH₃ II. -CHCH₂ III. -CCH IV. -CH₃

Identify the relationship between these two structures.

What is the relationship of the following two structures?

Which of the following choices is a diastereomer of the first structure shown.

Draw the enantiomer of the following compound.

Assign the absolute configuration of the chirality center as R or S.